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《Composite Interfaces》2013,20(4):441-451
The influence of interfacial reaction on interfacial performance of carbon fiber/polyarylacetylene resin composites was studied. For this purpose, vinyltrimethoxysilane containing a double bond was grafted onto the carbon fiber surface to react with the triple bond of polyarylacetylene resin. The reaction between polyarylacetylene resin and vinyltrimethoxysilane was proved by reference to the model reaction between phenylacetylene and vinyltrimethoxysilane. Surface chemical analysis by XPS, surface energy determination from the dynamic contact angle, and the interfacial adhesion in composites was evaluated by interfacial shear strength test as well. It was found that vinyltrimethoxysilane, which can react with polyarylacetylene resin, had been grafted onto the carbon fiber surface. Furthermore, because the reaction between polyarylacetylene resin and vinyltrimethoxysilane took place at the interface, the interfacial adhesion in composites was significantly increased, and the improvement of interfacial adhesion was all attributed to the interfacial reaction. 相似文献
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Guochun Wen 《分析论及其应用》2005,21(2):118-131
The present paper deals with the mixed boundary value problem for elliptic equations with degenerate rank 0. We first give the formulation of the problem and estimates of solutions of the problem, and then prove the existence of solutions of the above problem for elliptic equations by the above estimates and the method of parameter extension. We use the complex method, namely first discuss the corresponding problem for degenerate elliptic complex equations of first order, afterwards discuss the above problem for degenerate elliptic equations of second order. 相似文献
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傅-克反应是有机化学中最基本的反应之一,但是对于催化的不对称傅-克反应的研究则处于起步阶段。最近这方面的研究获得了突破,本文简要介绍了催化不对称傅-克反应的最新动态,包括各种手性Lewis酸催化体系的开发及其在不对称合成中的应用。 相似文献
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